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Dicobalt octacarbonyl 八羰基二鈷

規格: 98%
CAS: 10210-68-1
產品編號: H25839
MDL: MFCD00016024
品牌: INFI
Chemical NameOctacarbonyldicobalt
CAS Number10210-68-1
Synonym Cobalt Carbonyl (Stabilized with 1-5% Hexane) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00016024
PubChem Substance ID87559522
EC Number233-514-0
Reaxys-RN17425010
Chemical Name Translation八羰基二鈷
LabNetwork Molecule IDLN01816957
Merck Number3085
Canonical SMILES[Co+2].[Co+2].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 378 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 38(1),97,1973

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 26900 ug/m3/2H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   VRDEA5 Vrachebnoe Delo.  Medical Practice.  (V/O Mezhdunarodnaya Kniga,
   113095 Moscow, USSR) No.1-    1918-  Volume(issue)/page/year: (2),101,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 165 mg/m3
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   VRDEA5 Vrachebnoe Delo.  Medical Practice.  (V/O Mezhdunarodnaya Kniga,
   113095 Moscow, USSR) No.1-    1918-  Volume(issue)/page/year: (2),101,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 754 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 38(1),97,1973

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。
  • P302+P352+P333+P313+P362+P364
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
  • P304+P340+P310
  • P501 Dispose of contents/container to..… 處理內容物/容器.....
  • P301+P312+P330
  • P302+P350
  • P337+P313
  • P308+P313
  • P403+P233
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
  • P284 Wear respiratory protection.? 佩戴呼吸保護裝置。
  • P201 Obtain special instructions before use. 使用前獲取專門指示。
  • P270 Do not eat, drink or smoke when using this product. 使用本產品時不要吃東西，喝水或吸煙。
  • P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
  • P273 Avoid release to the environment. 避免釋放到環境中。
  • P305+P351+P338+P337+P313
  • P405 Store locked up. 上鎖保管。
  • P202 Do not handle until all safety precautions have been read and understood. 已閱讀并理解所有的安全預防措施之前，切勿操作。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得帶出工作場所。
    Signal word Danger
    Hazard statements
    • H302 Harmful if swallowed 吞食有害
    • H315 Causes skin irritation 會刺激皮膚
    • H330 Fatal if inhaled 吸入致命
    • H317 May cause an allergic skin reaction 可能導致皮膚過敏
    • H351 Suspected of causing cancer 懷疑致癌
    • H361 Suspected of damaging fertility or the unborn child 懷疑對生育能力或未出生嬰兒造成傷害
    • H304 May be fatal if swallowed and enters airways 吞食和進入呼吸道可能致命
    • H251 Self-heating: may catch fire 自我放熱：可能著火
    • H373 May causes damage to organs through prolonged or repeated exposure 長期或頻繁接觸可能會損傷器官
    • H412 Harmfutoaquaticlifewithlonglastingeffects 對水生生物有害并具有長期影響。
      WGK Germany3
      RTECSGG0300000
      Safety Statements
      • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免釋放到環境中，參考特別指示/安全收據說明書；
      • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時，立即求醫（可能時出示標簽）；
      • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮膚接觸后，立即用大量…（由生產廠家指定）沖洗；
      • S36/37 Wear suitable protective clothing and gloves 穿戴適當的防護服和手套；
        Packing GroupII
        UN Number 3466
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R52/53
        • R40 Limited evidence of a carcinogenic effect 有限證據表明其致癌作用
        • R22 Harmful if swallowed 吞咽有害
        • R43 May cause sensitisation by skin contact 皮膚接觸會產生過敏反應
        • R26 Very toxic by inhalation 吸入極毒
        • R48/20
        • R62 Possible risk of impaired fertility 有削弱生殖能力的危險
          Storage condition +4°C +4℃ -20°C 0-10 0-10°C 2-8°C, stored under nitrogen Air Sensitive {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
          Hazard Codes T+ F,T+
          Hazard Class6.1
          Restrict 危險品
        • Cobalt Carbonyl is a metal carbonyl used as a reagent and catalyst in organometallic chemistry and organic synthesis. Cobalt Carbonyl is commonly used as a hydroformylation catalyst for the conversion
        • {ALF}
        • {
        • {uni_hamburg} Short: III/20b
        • {uni_hamburg} Short: III/35D5
        • {TRC} Mirbach, M. et al.: J. Am. Chem. Soc., 103, 7594 (1981); Haukka, M. et al.: J. Mol. Cat. A Chem., 102, 79 (1995); Haumann, M. et al.: Catal. Tod., 79, 43 (2003);
        • {ALF} The reaction has been exploited as a powderful tool in the synthesis of complex molecules. For reviews, see: Org. React., 40, 1 (1991); Chem. Soc. Rev., 33, 32 (2004).
        • {ALF} Reagent used in the Pauson-Khand reaction, a formal [2 + 2 + 1] cycloaddition of an alkyne, and alkene and carbon monoxide to form a cyclopentenone: J. Chem. Soc., Perkin 1, 977 (1973):
          • 10210-68-1 H25839 Dicobalt octacarbonyl 八羰基二鈷
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          化學屬性

          Mol. FormulaC8Co2O8
          Mol. Weight341.95
          Density1.73
          Flash Point-9°F (hexane)
          SolubilityInsoluble in water. Soluble in alcohol, ether and carbon disulfide
          TSCAYes
          Melting Point51-52 °C
          Boiling Point52 °C at 760 mmHg
          Appearance dark orange xtl.
          Stabilityair sensitive, store cold
          Danger-Level-
          pH-:-
          Redox-

          *以上化合物性質及應用等信息僅供參考