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Sodium cyclopentadienylide 環戊二烯化鈉

規格: 2.0 M solution in THF, SpcSeal
CAS: 4984-82-1
產品編號: H37161
MDL: MFCD00012161
品牌: INFI
Chemical NameSodium Cyclopentadienide
Synonym (2,4-Cyclopentadienyl) sodium 2,4-Cyclopentadien-1-ylsodium 2,4-Cyclopentadienylsodium CYCLOPENTADIENYLSODIUM CYCLOPENTADIENYLSODIUM SOLUTION, ~2 M IN THF Cyclopentadienylsodium solution NACP Na-cyclopentadienide Natriumcyclopentadienylid SODIUM CYCLOPENTADIENIDE SODIUM CYCLOPENTADIENIDE 2.0 M IN THF SODIUM CYCLOPENTADIENYLIDE Sodium Cyclopentadienide, approx. 20 wt% in THF/Toluene Sodium, 2,4-cyclopentadien-1-yl- Sodium, 2,4-cyclopentadienide Sodium, cyclopentadienyl- Sodiumcyclopentadiene 環戊二烯化鈉 環戊二烯化鈉, 2-3M IN THF 環戊二烯基鈉 溶液 環戊二烯基鈉 溶液;環戊二烯化鈉 環戊二烯基鈉，四氫呋喃溶液
MDL NumberMFCD00012161
CAS Number4984-82-1
EC Number225-636-8
Beilstein Registry Number969542
PubChem Substance ID78681
Chemical Name Translation環戊二烯化鈉
InChIKeyPDTZVKVFAJGNRV-UHFFFAOYSA-N
LabNetwork Molecule IDLN02124362
InChIInChI=1S/C5H5.Na/c1-2-4-5-3-1;/h1-5H;/q-1;+1
GHS Symbol
Signal word Danger
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 遠離火源，禁止吸煙；
  • S20 When using do not eat or drink 使用時，不得進食，飲水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入氣體/煙霧/蒸汽/噴霧；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見；
  • S30 Never add water to this product 切勿將水加入該產品中；
  • S33 Take precautionary measures against static discharges 對靜電采取預防措施；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護；
  • S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 著火時使用（指明具體的消防器材種類，如果用水增加危險，注明“禁止用水”
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時，立即求醫（可能時出示標簽）；
  • S60 This material and its container must be disposed of as hazardous waste 該物質及其容器必須作為危險廢物處置；
  • S7/8 Keep container tightly closed and dry 保存在嚴格密閉容器中，保持干燥；
  • S8 Keep container dry 保持容器干燥；
  • S9 Keep container in a well-ventilated place 保持容器在通風良好的場所；
    Risk Statements
    • R11 Highly flammable 非常易燃
    • R14 Reacts violently with water 遇水會猛烈反應
    • R15 Contact with water liberates extremely flammable gases 遇水會釋放出極端易燃的氣體
    • R19 May form explosive peroxides 可能生成易爆的過氧化物質
    • R34 Causes burns 會導致灼傷
    • R35 Causes severe burns 會導致嚴重灼傷
    • R37 Irritating to respiratory system 刺激呼吸道
    • R40 Limited evidence of a carcinogenic effect 有限證據表明其致癌作用
      Precautionary statements
      • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 遠離熱源/火花/明火/熱的表面。——禁止吸煙。
      • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 遠離任何與水接觸的可能，因為會劇烈反應可能產生閃火。
      • P231+P232
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
      • P370+P378
      • P422 Store contents under… 存儲目錄在…之下。
        Hazard statements
        • H314 Causes severe skin burns and eye damage 導致嚴重的皮膚灼傷和眼睛損傷
        • H351 Suspected of causing cancer 懷疑致癌
        • H260 In contact with water releases flammable gases which may ignite spontaneously 與水接觸時釋放可燃氣體，可自燃。
        • H225 Highly flammable liquid and vapour 高度易燃液體和蒸氣
        • H335 May cause respiratory irritation 可能導致呼吸道刺激
        • H302 Harmful if swallowed 吞食有害
          Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
          Packing GroupII
          UN Number 1993 UN 1993 3/PG 2
          Storage condition Air & Moisture Sensitive 2-8°C 充氬注射劑瓶包裝 充氬保存
          Hazard Codes 3 F,C F,Xi
          Hazard Class4.3
          Restrict -
        • 可用于制備茂金屬和環戊二烯基金屬絡合物的有效試劑。
        • 用于由二苯基膦基炔烴和 CoCl(PPh3)3 制備環戊二烯鈷化合物。
        • {uni_hamburg} Short: III/35D5
        • {uni_hamburg} Short: EINECS
        • {ALD} Beilstein: 16,IV,1698
          • 4984-82-1 H37161 Sodium cyclopentadienylide 環戊二烯化鈉
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          化學屬性

          Mol. FormulaC5H5Na
          Mol. Weight88.08
          Density0.94
          Flash Point1 °F
          TSCAYes
          Boiling Point65-67
          Stability對空氣和濕度敏感
          Appearance yellow to red solution
          Danger-Level-
          pH-:-
          Redox-

          *以上化合物性質及應用等信息僅供參考