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Bis(cyclopentadienyl)zirconium dichloride 二氯二茂鋯

規格: 98%
CAS: 1291-32-3
產品編號: H76122
MDL: MFCD00003726
品牌: INFI
Chemical NameBis(cyclopentadienyl)zirconium dichloride
Synonym Bis(cyclopentadienyl)zirconium(IV) dichloride {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentadienyl)zirconium(IV) dichloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(cyclopentad
CAS Number1291-32-3
EC Number215-066-8
Beilstein Registry Number2384789
MDL NumberMFCD00003726
PubChem Substance ID87577925
Chemical Name Translation二氯二茂鋯
Wiswesser Line NotationL50J 0-ZR-GG- 0L50J
LabNetwork Molecule IDLN01746727
Canonical SMILES[][Zr](Cl)(Cl)[].c1cccc1.c2cccc2
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 30 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the
   National Cancer Institute by The Institute of Chemical Biology, University
   of San Francisco.  (San Francisco, CA 94117)  Volume(issue)/page/year:
   PH43-64-886

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

Signal word Danger
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接觸后，立即用大量水沖洗并征求醫生意見；
  • S36 Wear suitable protective clothing 穿戴適當的防護服；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴適當的防護服、手套和眼睛/面保護；
  • S37 Wear suitable gloves 戴適當手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 發生事故時或感覺不適時，立即求醫（可能時出示標簽）；
  • S60 This material and its container must be disposed of as hazardous waste 該物質及其容器必須作為危險廢物處置；
  • S9 Keep container in a well-ventilated place 保持容器在通風良好的場所；
    Risk Statements
    • R34 Causes burns 會導致灼傷
    • R36/37/38 Irritating to eyes, respiratory system and skin 對眼睛、呼吸系統和皮膚有刺激性
      Precautionary statements
      • P234 Keep only in original container. 只保留在原來的容器中。
      • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
      • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉塵/煙/氣體/煙霧/蒸汽/噴霧。
      • P264 Wash hands thoroughly after handling. 處理后要徹底洗凈雙手。
      • P270 Do not eat, drink or smoke when using this product. 使用本產品時不要吃東西，喝水或吸煙。
      • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通風良好的地方使用。
      • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防護手套/防護服/眼睛的保護物/面部保護物。
      • P301+P330+P331
      • P303+P361+P353
      • P303+P361+P353+P310+P363
      • P305+P351+P338
      • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或醫生/醫師。
      • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大損害。
      • P405 Store locked up. 上鎖保管。
      • P501 Dispose of contents/container to..… 處理內容物/容器.....
        RTECSZH7525000
        Hazard statements
        • H315 Causes skin irritation 會刺激皮膚
        • H319 Causes serious eye irritation 嚴重刺激眼睛
        • H335 May cause respiratory irritation 可能導致呼吸道刺激
        • H290 May be corrosive to metals 可能腐蝕金屬。
          Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
          Packing GroupIII
          UN Number 3261
          Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Air & Moisture Sensitive Refrigerator (+4°C) {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitro
          Hazard Codes 8 Xi
          Hazard Class8
        • 用于合成許多早期過渡金屬絡合物和有機金屬化合物
        • {uni_hamburg} Short: III/35D5
        • {ALF}
        • {uni_hamburg} Short: III/20b
        • {ALF} For reaction of alkene-zirconocene complexes with cyclic enol ethers, see: Angew. Chem. Int. Ed., 43, 3932 (2004).
        • {ALF} Versatile organometallic reagent and catalyst. For a brief review, see: Synlett, 375 (1999). Other reviews: Organozirconium compounds in organic synthesis: Synthesis, 1 (1988); Recent advances in the chemistry of zirconocene and related compounds: Tetrahedron, 51, 4255 (1995); Synthetic applications of zirconocene complexes: Tetrahedron, 52, 12853 (1996). Formation of carbon-carbon bonds via 'zirconocene' (obtained by reaction of the dichloride with Grignard or lithium reagents): Synlett, 299 (1995). Reduction with n-BuLi in the presence of 2-butyne leads to a zirconium metallocycle: Tetrahedron Lett., 27, 2829 (1986), which is a useful intermediate for the synthesis of phospholes and analogous heterocycles in which the Zr atom is replaced by As, Sb, Bi, Si, Ge, Sn, Ga, S, Se or B: Org. Synth. Coll., 9, 653 (1998), and references therein:
          • 1291-32-3 H76122 Bis(cyclopentadienyl)zirconium dichloride 二氯二茂鋯
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          化學屬性

          Mol. FormulaC10H10Cl2Zr
          Mol. Weight292.32
          Density1.422
          Melting Point242-245°C
          TSCAYes
          Boiling Point124-125 °C at 15 mmHg
          Solubility水解
          Stability對濕度敏感
          Flash Point124-125°C/15mm
          Appearance white to off-white pwdr.
          RedoxReduction

          *以上化合物性質及應用等信息僅供參考